石油化工2017,Vol.46Issue(6):726-730,5.DOI:10.3969/j.issn.1000-8144.2017.06.012
外给电子体对聚丙烯结晶性能的影响
The effect of external donors on crystallization properties of polypropylene
摘要
Abstract
Three kinds of polypropylenes(PPs) with different isotacticity and relative molecular mass were prepared by using three kinds of alkylsiloxane external donors.The effects of extemal donors on crystallization properties of PPs were introduced.The isothermal crystallization of the three kinds of PPs was tested by DSC and POM.The results showed that the isotacticity and relative molecular mass of PPs increased with the volume of alkylsiloxane as external donors.As increasing the crystallization temperature,the crystallization rate of PPs decreased.关键词
聚丙烯/外给电子体/等温结晶/等规度/结晶速率Key words
polypropylene/external donor/isothermal crystallization/tacticity/crystallization rate分类
化学化工引用本文复制引用
周倩,黄河,张辽云,李磊,李化毅..外给电子体对聚丙烯结晶性能的影响[J].石油化工,2017,46(6):726-730,5.基金项目
中国科学院分子科学科教融合创新项目 ()
国家自然科学基金项目(51073170). (51073170)