中国塑料2017，Vol.31Issue(8)：30-34,5.DOI:10.19491/j.issn.1001-9278.2017.08.005
含改性季戊四醇的辐照阻燃交联聚烯烃的性能研究
Study on Properties of Irradiation-crosslinked Flame-retardant Polyolefin Containing Modified Pentaerythritol
张文龙 1李月 2金姗姗 1史培建 1戴亚杰1
作者信息
- 1. 哈尔滨理工大学材料科学与工程学院,黑龙江哈尔滨150040
- 2. 哈尔滨理工大学工程电介质及其应用教育部重点实验室,黑龙江哈尔滨150080
- 折叠
摘要
Abstract
Irradiation-crosslinked polyolefin composites were prepared by ethylene-vinyl acetate copolymer with intumescent flame retardant (IFR)of modified pentaerythritol as char-forming agent through melt blending,and their flame retardant performance,electrical properties and thermal stability were investigated by limiting oxygen index,high resistance meter,breakdown tester and thermogravimetic analysis.The results indicated that,when 40 wt ％ of the complex flame retardants was introduced and the irradiation dose was less than 90 kGy,the resulting EVA/IFR-MPER systems achieved an improvement in flame retardancy by 1.5 ％.Furthermore,their breakdown field strength,volume resistivity,maximum decomposition temperature and carbon yield at 600 ℃ increased by 2.2 MV/m,0.6 × 1013 Ω · m,4.43 ℃ and 8.52 ％,respectively.关键词
改性季戊四醇/乙烯-醋酸乙烯共聚物/辐照/阻燃Key words
modified pentaerythritol/ethylene-vinyl acetate copolymer/irradiation/flame retardant分类
化学化工引用本文复制引用
张文龙,李月,金姗姗,史培建,戴亚杰..含改性季戊四醇的辐照阻燃交联聚烯烃的性能研究[J].中国塑料,2017,31(8):30-34,5.
