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水性聚氨酯的合成及可剥涂料的性能研究

丁祖群 傅念清 王云英

表面技术2017,Vol.46Issue(9):60-65,6.
表面技术2017,Vol.46Issue(9):60-65,6.DOI:10.16490/j.cnki.issn.1001-3660.2017.09.010

水性聚氨酯的合成及可剥涂料的性能研究

Synthesis of Waterborne Polyurethane and the Properties of Strippable Coating

丁祖群 1傅念清 2王云英2

作者信息

  • 1. 中航工业成都飞机工业(集团)有限责任公司 制造工程部,成都 610091
  • 2. 南昌航空大学 材料科学与工程,南昌 330063
  • 折叠

摘要

Abstract

A waterborne polyurethane is used as the main film-forming material to prepare a protective coating with good water resistance. The synthesis process of waterborne polyurethane is analyzed by orthogonal method. The influence of triethy-lamine and H2O content on the properties of the product is analyzed by testing the FTIR, storage time, exterior and water resis-tance. Then, the synthesis product is used as the base material, The polycarbodiimide and other additives are used to prepare waterborne coatings. The protective and strippable properties of the waterborne coating are analyzed by testing Shore hardness, adhesion, tensile strength, elongation at break, peel strength and water resistance. the waterborne polyurethane is successfully synthesized, and the optimum synthesis process of the self-emulsifying waterborne polyurethane is obtained. The coating pro-cessability and the coating performance are good, and the coating can be peeled off in one time. The coating has good water re-sistance: After soaking in room temperature for 48 h, the quality is basically unchanged, The tensile strength is changed from 37.7 MPa to 33.6 MPa, the elongation at break from 540% to 510%, and the Shore hardness is still for the 82HA; The addition of polycarbodiimide and other additives makes the coating has good peelability and water resistance, and the coating hardness of 82HA, the substrate can play a protective role.

关键词

自乳化型水性聚氨酯/聚碳化二亚胺/可剥性/耐水性

Key words

waterborne polyurethane/polycarbodiimide/peelability/water resistance

分类

化学化工

引用本文复制引用

丁祖群,傅念清,王云英..水性聚氨酯的合成及可剥涂料的性能研究[J].表面技术,2017,46(9):60-65,6.

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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