电池2017，Vol.47Issue(3)：133-136,4.DOI:10.19535/j.1001-1579.2017.03.002
冷等静压法制备Li7La3Zr2O12固体电解质
Preparing Li7La3Zr2O12 solid electrolyte by cold isostatic pressing method
摘要
Abstract
Cold isostatic pressing method was employed to prepare Li7La3Zr2O12 (LLZO) solid state electrolyte.The crystalline structure,morphology,and electrochemical performance were characterized by XRD,SEM,AC impedance spectrum,Hebb-Wagner and cyclic voltammetry measurements.When the sintering temperature reached up to 1 150 ℃,a dense and pure cubic structure LLZO pellet was gained,with a total ionic conductivity of 1.07 × 10-4 S/cm and an electronic conductivity of 2.39 × 10-8 S/cm at room temperature.This sample was determined to be a nice ion conductor and electron insulator.In a wide electrochemical stable widow of 0-7 V(vs.Li +/Li),no distinct redox reaction was detected.关键词
锂离子电池/固体电解质/离子导电率/电子导电率/冷等静压法Key words
Li-ion battery/solid state electrolyte/ionic conductivity/electronic conductivity/cold isostatic pressing method分类
信息技术与安全科学引用本文复制引用
赵鹏程,祝夏雨,曹高萍,文越华..冷等静压法制备Li7La3Zr2O12固体电解质[J].电池,2017,47(3):133-136,4.基金项目
国家重点研发计划(2016YFB0901500) （2016YFB0901500）
