电源技术2017,Vol.41Issue(9):1292-1295,4.
PEI-GNs/PMo12复合膜负载Pd对甲酸氧化催化性能研究
Study on preparation of PEI-GNs/PMo12 composite film supported Pd catalysts and its electro-oxidation for formic acid
摘要
Abstract
The LBL method was used to synthesize PEI-GNs/PMo12 composite film.The Pd/PEI-GNs/PMo12 catalyst was prepared by the electrochemical deposition technique with PEI-GNs/PMo12 composite film as the carrier.The as-prepared catalyst was characterized by XRD,XPS and SEM.It was shown that Pd particles were well dispersed on the PEI-GNs/PMo12 substrate.The performance of the Pd/PEI-GNs/PMo12 catalyst toward formic acid oxidation was examined by electrochemical technique.Comparing with the Pd catalyst,the as-prepared Pd/PEI-GNs/PMo12 catalyst presented better electrocatalytic activity and stability towards formic acid oxidation reaction.The enhancement in electrochemical activity of the Pd/PEI-GNs/PMo12 catalyst could be attributed to the well dispersed Pd nanoparticles on the carrier and higher electron transfer of PEI-GNs/PMo12.关键词
复合膜/Pd纳米粒子/甲酸/电催化氧化Key words
composite film/Pd nanoparticles/formic acid/electro-oxidation分类
信息技术与安全科学引用本文复制引用
罗明洪..PEI-GNs/PMo12复合膜负载Pd对甲酸氧化催化性能研究[J].电源技术,2017,41(9):1292-1295,4.基金项目
江西省教育厅科技项目(GJJ161237) (GJJ161237)
南昌师范学院科研重点项目(16KJZD01) (16KJZD01)
南昌师范学院重点学科建设项目(NSXK-20141003) (NSXK-20141003)