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PEI-GNs/PMo12复合膜负载Pd对甲酸氧化催化性能研究

罗明洪

电源技术2017,Vol.41Issue(9):1292-1295,4.
电源技术2017,Vol.41Issue(9):1292-1295,4.

PEI-GNs/PMo12复合膜负载Pd对甲酸氧化催化性能研究

Study on preparation of PEI-GNs/PMo12 composite film supported Pd catalysts and its electro-oxidation for formic acid

罗明洪1

作者信息

  • 1. 南昌师范学院化学系,江西南昌330022
  • 折叠

摘要

Abstract

The LBL method was used to synthesize PEI-GNs/PMo12 composite film.The Pd/PEI-GNs/PMo12 catalyst was prepared by the electrochemical deposition technique with PEI-GNs/PMo12 composite film as the carrier.The as-prepared catalyst was characterized by XRD,XPS and SEM.It was shown that Pd particles were well dispersed on the PEI-GNs/PMo12 substrate.The performance of the Pd/PEI-GNs/PMo12 catalyst toward formic acid oxidation was examined by electrochemical technique.Comparing with the Pd catalyst,the as-prepared Pd/PEI-GNs/PMo12 catalyst presented better electrocatalytic activity and stability towards formic acid oxidation reaction.The enhancement in electrochemical activity of the Pd/PEI-GNs/PMo12 catalyst could be attributed to the well dispersed Pd nanoparticles on the carrier and higher electron transfer of PEI-GNs/PMo12.

关键词

复合膜/Pd纳米粒子/甲酸/电催化氧化

Key words

composite film/Pd nanoparticles/formic acid/electro-oxidation

分类

信息技术与安全科学

引用本文复制引用

罗明洪..PEI-GNs/PMo12复合膜负载Pd对甲酸氧化催化性能研究[J].电源技术,2017,41(9):1292-1295,4.

基金项目

江西省教育厅科技项目(GJJ161237) (GJJ161237)

南昌师范学院科研重点项目(16KJZD01) (16KJZD01)

南昌师范学院重点学科建设项目(NSXK-20141003) (NSXK-20141003)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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