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含铁氮化硅的氧化行为

管甲锁 成来飞 王耀辉

硅酸盐学报2017,Vol.45Issue(9):1335-1339,5.
硅酸盐学报2017,Vol.45Issue(9):1335-1339,5.DOI:10.14062/j.issn.0454-5648.2017.09.16

含铁氮化硅的氧化行为

Oxidation Behavior of Silicon Nitride Containing Iron

管甲锁 1成来飞 1王耀辉1

作者信息

  • 1. 西北工业大学,超高温结构复合材料国防科技重点实验室,西安 710072
  • 折叠

摘要

Abstract

The oxidation behavior of silicon nitride ceramics containing iron in air at 1300-1500 ℃ was investigated. The results indicate that the presence of iron in the ceramics causes a slight increase in the oxidation rate. The oxidation of Fe-Si3N4 obeys the parabolic oxidation law, with an activation energy of 285 kJ/mol. Based on the element mapping analysis, iron diffused to the surface during the oxidation process, causing a decrease in the oxidation resistance. However, the oxidation rate of Fe-Si3N4 is still appropriate for applications in air at high temperatures.

关键词

氮化硅/氮化硅铁/氧化/活化能

Key words

silicon nitride/ferrosilicon nitride/oxidation/activation energy

引用本文复制引用

管甲锁,成来飞,王耀辉..含铁氮化硅的氧化行为[J].硅酸盐学报,2017,45(9):1335-1339,5.

基金项目

国家自然科学基金重点项目(51632007)资助. (51632007)

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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