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腰果酚聚氧乙烯醚的表面性能研究

赵雪华 黄中瑞 康文倩 王利民 车飞 翟兆凯

日用化学工业2017,Vol.47Issue(9):492-496,5.
日用化学工业2017,Vol.47Issue(9):492-496,5.DOI:10.13218/j.cnki.csdc.2017.09.003

腰果酚聚氧乙烯醚的表面性能研究

Study on the surface performance of cardanol polyoxyethylene ether

赵雪华 1黄中瑞 2康文倩 2王利民 2车飞 1翟兆凯2

作者信息

  • 1. 上海市功能性材料化学重点实验室,上海 200237
  • 2. 华东理工大学化学与分子工程学院精细化工研究所,上海 200237
  • 折叠

摘要

Abstract

Surface activity of cardanol polyoxyethylene ether BGF-10 and the effects of different additives on the surface activity were studied. Results show that the critical micelle concentration (cmc)of BGF-10 is 6. 09 × 10 -6 mol/L,and the lowest surface tension (γcmc )is 38. 08 mN/m at 25 ℃. Moreover,BGF -10 displays a better resistance to hard water and a strong salt tolerance to monovalent inorganic salts. With the increase of concentration of divalent inorganic salt,the surface activity of BGF-10 is enhanced. Monohydric alcohol can reduce the surface tension of BGF-10 . The ability of BGF-10 to form micelles increases in the beginning and then decreases with the increase of monohydric alcohol concentration. BGF -10 displays a synergistic effect with other surfactants,especially with hexadecyltrimethylammonium bromide (CTAB),and its cmc synergizes upto 2. 52%,while the γcmc synergizes upto 11. 49%. BGF -10 displays a good emulsifying power for paraffin oil,as well as both thickening and defoaming performance.

关键词

腰果酚聚氧乙烯醚/临界胶束浓度/表面张力/复配

Key words

cardanol polyoxyethylene ether/critical micelle concentration/surface tension/blending

分类

化学化工

引用本文复制引用

赵雪华,黄中瑞,康文倩,王利民,车飞,翟兆凯..腰果酚聚氧乙烯醚的表面性能研究[J].日用化学工业,2017,47(9):492-496,5.

基金项目

国家自然科学基金资助项目(21272069) (21272069)

日用化学工业

OA北大核心CSCDCSTPCD

1001-1803

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