物理化学学报2017,Vol.33Issue(8):1614-1620,7.DOI:10.3866/PKU.WHXB201704181
可用作便携式电源的高性能直接碳固体氧化物燃料电池组
A High Performance Direct Carbon Solid Oxide Fuel Cell Stack for Portable Applications
摘要
Abstract
A direct carbon solid oxide fuel cell (DC-SOFC) stack was prepared with 3 tubular cells electrically connected in sedes.To increase carbon storage in the stack,the anode was fabricated outside the tubular cells so that carbon fuel can be loaded at the extedor of the stack,which is more spacious than the interior.The 3-cell-stack is operated directly with carbon as the fuel and oxygen in ambient air as the oxidant.With a total effective area of 10.2 cm2 and a 5% (w) Fe-loaded activated carbon fuel of 17 g,the stack reveals a peak power of 4.1 W at 800 ℃.The stack discharged at a constant current of 1.0 A for 19 h,giving a charge capacity of 19 A·h and an energy capacity of 31.6 W·h,which are much higher than those of a similar stack with anode on the inside and carbon loaded at the interior.The high capacity of our DC-SOFC opens up potential applications in portable devices.关键词
固体氧化物燃料电池/碳燃料/锥管串接电池组/碳空气电池/便携式应用装置Key words
Solid oxide fuel cell/Carbon fuel/Segmented-in-series stack/Carbon-air battery/Portable application分类
化学化工引用本文复制引用
王晓强,刘江,谢永敏,蔡位子,张亚鹏,周倩,于方永,刘美林..可用作便携式电源的高性能直接碳固体氧化物燃料电池组[J].物理化学学报,2017,33(8):1614-1620,7.基金项目
The project was supported by the National Natural Science Foundation of China (21276097,21567008,21263005),Special Funds of Guangdong Province Public Research and Ability Construction,China (2014A010106008),Guangdong Innovative and Entrepreneurial Research Team Program,China (2014ZT05N200),and Program of Excellent Ph.D Thesis Authors of Guangdong Province,China.国家自然科学基金(21276097,21567008,21263005),广东省公共研究与能力建设专项资金(2014A010106008),广东省创新企业团队项目(2014ZT05N200),广东省优秀博士论文项目资助 (21276097,21567008,21263005)