材料科学与工程学报2017，Vol.35Issue(4)：538-541,4.DOI:10.14136/j.cnki.issn 1673-2812.2017.04.005
P3HT聚集体结构对有机太阳电池效率的影响
Influence of Aggregate Structure of P3HT Nanoparticles on the Performance of Organic Solar Cells
摘要
Abstract
To explore the relationship between the aggregate structure of active layers and the power conversion efficiency (PCE) of organic solar cells (OSCs),serials of poly (3-hexylthiophene) (P3HT) nanoparticles (NPs) with uniform size,good dispersity and ordered molecular packing were prepared via adding poor solvent of acetone or n-hexane into P3HT chloroform solution with different dropping times.Atomic force microscope (AFM),ultraviolet-visible (UV-Vis) absorption spectroscopy and X-ray diffraction were used to characterize the size,morphology and crystallinity of P3HT NPs.Blending P3HT NPs with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as active layer,we fabricated serials of bulk-heterojunction OSCs and found that the devices based on P3HT NPs with similar size but ordered structure along π-π stacking direction showed better performance.关键词
纳米颗粒/结晶有序性/有机太阳电池Key words
nanoparticles/paracrystallinity/organic solar cells分类
信息技术与安全科学引用本文复制引用
代帅,陈红征..P3HT聚集体结构对有机太阳电池效率的影响[J].材料科学与工程学报,2017,35(4):538-541,4.基金项目
国家自然科学基金资助项目(91233114) （91233114）
