太原理工大学学报2017，Vol.48Issue(4)：557-562,6.DOI:10.16355/j.cnki.issn1007-9432tyut.2017.04.008
Cu/Co比调变对合成气制低碳醇CuCoCe催化剂性能的影响
Adjustment of the Mass Ratio of Cu/Co and Its Effect on the Performance of CuCoCe Catalyst for Higher Alcohol Synthesis from Syngas
摘要
Abstract
A series of CuCoCe/CNTs catalysts with different Cu/Co mass ratio were prepared by co-impregnation method to study the influence of the adjustment of Cu/Co mass ratio on the catalystic performance of the catalysts for higher alcohols synthesis from syngas.The catalyst showed highest space-time yield (783.72 mg · g-1 · h-1) and selectivity of higher alcohols (42.46％) while the selectivity of methanol in alcohol distribution was only 17.29％ when the mass ratio of Cu/Co was 2.Our research results show that the catalyst with Cu/Co wass ratio 2 had better crystal structure and dispersion of active metal particles and oxidation-reduction ability.Meantime,the carbon nanotube support had excellent confinement effect.All these characteristic made the catalytic activity improved significantly.关键词
低碳醇/合成气/CuCoCe催化剂/碳纳米管Key words
higher alcohols/syngas/CuCoCe catalyst/carbon nanotube分类
化学化工引用本文复制引用
游向轩,黄伟,樊金串,周由之,魏珺谊..Cu/Co比调变对合成气制低碳醇CuCoCe催化剂性能的影响[J].太原理工大学学报,2017,48(4):557-562,6.基金项目
国家自然科学基金重点资助项目:合成气高效转化集成工艺及其关键科学与技术问题的研究(21336006),国家科技支撑计划项目:煤基产业节能减排的关键技术研发与示范(2013BAC14B04)资助 （21336006）
