物理化学学报2017，Vol.33Issue(9)：1752-1764,13.DOI:10.3866/PKU.WHXB201704273
适用于HCCI的生物柴油替代混合物简化机理的构建及验证
Development and Validation of a Reduced Chemical Kinetic Mechanism for HCCI Engine of Biodiesel Surrogate
摘要
Abstract
A simplified mechanism of methyl decanoate and n-heptane blend was developed for a homogeneous charge compression ignition engine built from a previously reported detailed mechanism of a methyl decanoate and n-heptane.The simplified mechanism with 113 species and 306 reactions was developed using path flux and temperature sensitivity analyses.The simplified mechanism was validated against the experimental data of ignition delay time,in-cylinder pressure,and CO emissions.Results show that the simplified mechanism not only coincides with the ignition delay time of the methyl decanoate and n-heptane,but also the CO emissions,and can reproduce the variation of in-cylinder pressure.The simplified mechanism can be further validated by comparison with the detailed mechanism,which shows that the simplified mechanism can coincide with the in-cylinder pressure and temperature,and can reproduce the variation tendency of the core components.Thus,the reduced mechanism is a reasonable one.关键词
HCCI/生物柴油/葵酸甲酯/正庚烷/简化机理Key words
Homogeneous charge compression ignition (HCCI)/Biodiesel/Methyl decanoate/n-Heptane/Reduced mechanism分类
化学化工引用本文复制引用
肖杰,张博,郑朝蕾..适用于HCCI的生物柴油替代混合物简化机理的构建及验证[J].物理化学学报,2017,33(9):1752-1764,13.基金项目
The project was supported by the National Natural Science Foundation of China Program (51376202).国家自然科学基金资助项目(51376202) （51376202）
