物理化学学报2017，Vol.33Issue(9)：1822-1827,6.DOI:10.3866/PKU.WHXB201705022
柔性Pd@PANI/rGO纸阳极在甲醇燃料电池中的应用
Flexible Pd@PANI/rGO Paper Anode for Methanol Fuel Cells
钱慧慧 1韩潇 1肇研 1苏玉芹1
作者信息
- 1. 北京航空航天大学材料科学与工程学院,北京100191
- 折叠
摘要
Abstract
Polyaniline was synthesized on the surface of flexible graphene paper by pulse voltage method.The composite material was used as free-standing and binder-free electrode and catalyst support in methanol fuel cells with deposited Pd nanoparticles via cyclic voltammetry.The surface morphology and chemical composition of the material were analyzed by scanning electron microscopy,X-ray photoelectron spectroscopy,and infrared spectroscopy,and the electrocatalytic performance of the electrode was investigated.The results show that graphene paper is flexible,that this fabrication procedure is efficient,and that polyaniline on the surface of the graphene paper is homogeneous.The existence of polyaniline can improve catalytic efficiency since the methanol oxidation peak current density increased from 3 mA·mg-1 to 67 mA·mg-1 with the addition of polyaniline.The lifespan of the catalyst is also prolonged according to jdjb value (the oxidation peak current density ratio of forward scan and reverse scan) reaching 5.7.关键词
柔性石墨烯纸/聚苯胺/Pd纳米粒子/催化阳极/直接甲醇燃料电池Key words
Flexible graphene paper/Polyaniline/Pd nanoparticles/Catalytic anode/Direct methanol fuel cells分类
化学化工引用本文复制引用
钱慧慧,韩潇,肇研,苏玉芹..柔性Pd@PANI/rGO纸阳极在甲醇燃料电池中的应用[J].物理化学学报,2017,33(9):1822-1827,6.
