热带作物学报2017，Vol.38Issue(7)：1331-1336,6.DOI:10.3969/j.issn.1000-2561.2017.07.024
乙基多杀菌素在香蕉果实、 花瓣和土壤中的残留及消解动态分析
Analysis of Insecticide Residue and Digestion Dynamics of Spinetoram in Banana Fruits, Petals and Soil
摘要
Abstract
In order to evaluate the safety of spinetoram on banana, the residue and degradation dynamics of spinetoram in banana were detected by ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). The results showed that the limits of detection (LOD) of spinetoram in banana fruit, petal and soil were both 5 μg/kg. And the limits of quantification ( LOQ) were both validated calculated as 17 μg/kg. At the spiked levels of 0.01-0.20 mg/kg, the average recoveries of acetochlor in fruit, petal and soil were 89.6%-95.2%, 76.5%-89.8% and 75.8%-86.5%, and the relative standard deviations was 5.03%-7.10%, 5.16%-7.24% and 2.26%-5.83%, respectively. The half-lives of acetochlor in fruit, petal and soil was 5.6 d, 4.5 d and 6.5 d. Taken together, the findings reveal that spinetoram belongs to the easily degradable pesticide type. The present study suggests that UPLC-MS / MS could be applied to detect and analyze spinetoram residues and digestion dynamics in banana.关键词
乙基多杀菌素/香蕉/液相色谱-串联质谱/农药残留/消解动态Key words
Spinetoram/banana/liquid chromatography with tandem mass spectrometry/pesticide residue/dissipation dynamics分类
农业科技引用本文复制引用
夏西亚,付步礼,李强,邱海燕,乐渊,唐良德,刘奎..乙基多杀菌素在香蕉果实、 花瓣和土壤中的残留及消解动态分析[J].热带作物学报,2017,38(7):1331-1336,6.基金项目
现代农业产业技术体系建设专项资金(No. CARS-32-04) （No. CARS-32-04）
中央级科研院所基本业务费项目(No. 2016hzs1J007). （No. 2016hzs1J007）
