印染助剂2017，Vol.34Issue(10)：13-17,5.
硼硅丙烯酸酯合成及真丝织物接枝改性
Synthesis of borane-silicon containing acrylate and grafting modification on silk fabrics
摘要
Abstract
The target monomer 1- methacryloxyethyloxamethyl- 2- (1,1,1,3,3- pentamethyldisiloxanyl) car?borane (PMASC) was successfully prepared by reduction and substitution reaction, using 1- methacryloxyethy?loxamethyl carborane as raw material. The monomer PMASC was characterized by FT- IR and 1H NMR and then used to modify silk fabrics. The results of FT- IR and SEM confirmed that the target monomer had been grafted onto silk fabrics. The thermal stability of silk was estimated by TGA, DSC and MCC analysis. When the graft yield was 34.4%, the mass retention of grafted silk fabric was up to 34.2% under 800 ℃ and the endo?thermic peak for the thermal decomposition shifted toward higher temperature (343 ℃). It could be observed that the silk fabrics with higher graft yield exhibited greater heat- resistance.关键词
真丝/接枝改性/碳硼烷/耐热性Key words
silk/grafting modification/carborane/heat- resistance分类
化学化工引用本文复制引用
刘安琪,袁艳华,戴礼,李战雄..硼硅丙烯酸酯合成及真丝织物接枝改性[J].印染助剂,2017,34(10):13-17,5.基金项目
国家自然科学基金项目(51273140) （51273140）
