分析测试学报2017，Vol.36Issue(9)：1124-1128,5.DOI:10.3969/j.issn.1004-4957.2017.09.012
聚(3-氨基-5-巯基-1,2,4-三唑)/多壁碳纳米管修饰的玻碳电极同时检测尿酸、黄嘌呤与次黄嘌呤
Simultaneous Determination of Uric Acid, Xanthine and Hypoxanthine Based on poly(3-Amino-5-mercapto-1, 2, 4-triazole)/Multi-walled Carbon Nanotubes Modified Glassy Carbon Electrode
摘要
Abstract
In this paper,the poly (3-amino-5-mercapto-1,2,4-triazole)/multi-walled carbon nanotubes modified glassy carbon electrode(pTA/MWCNTs/GCE) was successfully prepared by electrodepositing 3-amino-5-mercapto-1,2,4-triazole(TA) on the MWCNTs/GCE.The electrochemical behaviors of uric acid (UA),xanthine (XA) and hypoxanthine (HX) at the pTA/MWCNTs/GCE were investigated using cyclic voltammetry (CV) and differential pulse voltammetry (DPV).The results showed that the chemically modified electrode displayed excellent electrochemical catalytic activities towards UA,XA and HX.The calibration curves for UA,XA and HX were obtained over the ranges of 9.0-739.0,2.0-259.0,1.0-353.0 μmoL/L with the detection limits of 0.67,0.17,0.33 μmol/L,respectively.In addition,the modified electrode was applied in the determination of UA,XA and HX in real samples (urine and serum),with the recoveries of the samples ranged between 98.8％-105.5％.关键词
多壁碳纳米管/3-氨基-5-巯基-1,2,4-三唑/尿酸/黄嘌呤/次黄嘌呤/电化学Key words
multi-walled carbon nanotubes/3-amino-5-mercapto-1, 2, 4-triazole/uric acid/xanthine/hypoxanthine/electrochemistry分类
化学化工引用本文复制引用
王存,张毅,孟丽,赵欣,王跃..聚(3-氨基-5-巯基-1,2,4-三唑)/多壁碳纳米管修饰的玻碳电极同时检测尿酸、黄嘌呤与次黄嘌呤[J].分析测试学报,2017,36(9):1124-1128,5.基金项目
重庆市工程技术研究中心建设项目(cstc2015yfpt_gcjsyjzx0027) （cstc2015yfpt_gcjsyjzx0027）
