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Co-BiVO4异质结光催化剂的制备及其性能

黄文迪 孙静 申婷婷 王西奎

化工进展2017,Vol.36Issue(11):4080-4086,7.
化工进展2017,Vol.36Issue(11):4080-4086,7.DOI:10.16085/j.issn.1000-6613.2017-0407

Co-BiVO4异质结光催化剂的制备及其性能

Preparation and properties of Co-doped BiVO4 heterojunction photocatalysts fabricated by hydrothermal method

黄文迪 1孙静 2申婷婷 2王西奎1

作者信息

  • 1. 齐鲁工业大学化学与制药工程学院,山东 济南 250353
  • 2. 齐鲁工业大学环境科学与工程学院,山东 济南250353
  • 折叠

摘要

Abstract

A unique Co-BiVO4 photocatalyst with heterostructure was synthesized via a simple one-step hydrothermal method. The material forms a p-n-type heterojunction structure by coating cobalt oxide on the surface of BiVO4. The morphology, structure, composition and optical property of the as-prepared nanocomposites were characterized by XRD, SEM, HRTEM, XPS, and UV-vis DRS. Characterization analysis showed that cobalt loaded on the surface of BiVO4 as oxide and the catalyst showed a significant red-shift in the absorption band in the visible region. The photocatalytic activities of the samples were examined by studying the degradation of methylene blue (MB) under visible-light irradiation. The results showed that the photocatalytic activity of Co-BiVO4 was increased by 4 times, compared with pure BiVO4 under visible light irradiation. The best photocatalytic activity was achieved when the molar ratio of Bi: Co was 1:2. The improving mechanisms of bismuth heterojunction and transition metal were further elucidating in the work.

关键词

催化剂/钴-钒酸铋/异质结/水热/降解

Key words

catalyst/Co-BiVO4/heterojunction/hydrothermal/degradation

分类

化学化工

引用本文复制引用

黄文迪,孙静,申婷婷,王西奎..Co-BiVO4异质结光催化剂的制备及其性能[J].化工进展,2017,36(11):4080-4086,7.

基金项目

国家自然科学基金项目(21507067). (21507067)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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