火炸药学报2017，Vol.40Issue(5)：24-29,55,7.DOI:10.14077/j.issn.1007-7812.2017.05.005
两种新型2-偕二硝甲基-5-硝基四唑含能离子盐的合成、表征及性能预估
Synthesis, Characterization and Performance Prediction of Two Kinds of Novel Energetic Ionic Salts of 2-Dinitromethyl-5-nitrotetrazolate
摘要
Abstract
Two kinds of novel energetic ionic salts of 2-dinitromethyl-5-nitrotetrazolate 3-amino-1,2,4-triazole salt (3-ATDNMNT) and 2-dinitromethyl-5-nitrotetrazolate 4-amino-1,2,4-triazole salt (4-ATDNMNT),were synthesized via neutralization reaction using amino-1,2,4 triazole and 2-dinitromethyl-5-nitrotetrazolate(HDNMNT) as raw materials.Their yields were 95.4％ and 96.7％,respectively.Their structures were characterized by means of FT-IR,1 H NMR,13C NMR,15 N NMR and elemental analysis.The detonation performances of 3-ATDNMNT and 4-ATDNMNT were calculated by quantum chemical method.Under the standard condition(expansion ratio as 70 ∶ 1),the energy performances of hydroxyl terminated polybutadicne (HTPB) composite propellant containing two kinds of energetic ion salts were calculated by the principle of minimum free energy.The results show that the detonation velocity and the detonation pressure are 8.587 km/s and 33.58 GPa for 3-ATDNMNT and 8.693 km/s and 34.31 GPa for 4-ATDNMNT,respectively.After partly replacing AP with 3-ATDNMNT in HTPB propellant,the theoretical specific impulse of HTPB propellant is up to 2 635.7 N · s/kg.After partly replacing AP with 4-ATD-NMNT in HTPB propellant,the highest theoretical impulse of HTPB propellant is 2 677.2 N · s/kg,when the mass fractions of HTPB,Al,AP and 4-ATDNMNT are 10％,5％,15％ and 70％,respectively.关键词
含能离子盐/2-偕二硝甲基-5硝基四唑3-氨基-1,2,4三唑盐/3-ATDNMNT/2-偕二硝甲基-5-硝基四唑4-氨基-1,2,4-三唑盐/4-ATDNMNT/爆轰性能/丁羟复合推进剂/HTPBKey words
energetic ionic salts/2-dinitromethyl-5-nitrotetrazolate 3-amino-1,2,4-triazole salt (3-ATDNMNT)/2-dinitromethyl-5-nitrotetrazolate 4-amino-1, 2,4-triazole salt (4-ATDNMNT)/detonation performance/HTPB composite propellant/HTPB分类
军事科技引用本文复制引用
张敏,许诚,葛忠学,毕福强,朱勇,卜建华,苏海鹏,肖啸..两种新型2-偕二硝甲基-5-硝基四唑含能离子盐的合成、表征及性能预估[J].火炸药学报,2017,40(5):24-29,55,7.基金项目
国家自然科学基金(No.21502148) （No.21502148）
