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钢渣中游离氧化镁含量的测定及其减量控制措施

马来君 连芳 王瀚霄 张作顺

矿产综合利用Issue(5):70-75,6.
矿产综合利用Issue(5):70-75,6.DOI:10.3969/j.issn.1000-6532.2017.05.015

钢渣中游离氧化镁含量的测定及其减量控制措施

Determination and Reduction of Free Periclase in Steel Slag

马来君 1连芳 1王瀚霄 1张作顺2

作者信息

  • 1. 北京科技大学材料科学与工程学院,北京100083
  • 2. 北京生态岛科技有限公司工艺技术部,北京102402
  • 折叠

摘要

Abstract

The poor stability derives from the hydration expansion of free periclase,which hinders the recycled utilization of steel slag as a partial replacement of cement.In the study,ammonium chloride-glycol extraction method has been optimized to determine precisely f-MgO content in steel slag.The results indicate that MgO component existing as RO and MgFe2O4 phase as well as other compositions in BOF slag show no influence on extraction and titration process,demonstrating the high accuracy of the method.Moreover,the mixture of iron tailings and limestone were used to modify the slag at high temperature.Under the modification at 1350℃ and water-cooling treatment,the free periclase content was decreased by 55.94%,from 2.02% to 0.89%.The results indicate that high temperature modification is a promising way to reduce significantly the content of f-MgO and improve the stability of BOF slag.

关键词

钢渣/安定性/游离氧化镁/滴定/高温改性

Key words

Steel slag/Stability/Free periclase/Extraction/High temperature modification

分类

矿业与冶金

引用本文复制引用

马来君,连芳,王瀚霄,张作顺..钢渣中游离氧化镁含量的测定及其减量控制措施[J].矿产综合利用,2017,(5):70-75,6.

基金项目

国家“十二五”科技支撑计划(2011BAB03B05)资助 (2011BAB03B05)

矿产综合利用

OA北大核心CSTPCD

1000-6532

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