日用化学工业2017，Vol.47Issue(10)：598-602,5.DOI:10.13218/j.cnki.csdc.2017.10.013
ICP-OES法同时测定化妆品中砷、铅和镉
Simultaneous determination of arsenic,lead and cadmium in cosmetics by ICP-OES
杨永超 1孙永泽 2张闯 1闫婧 1赵好力宝1
作者信息
- 1. 天津出入境检验检疫局,天津 300308
- 2. 天津国际生物医药联合研究院分析测试中心,天津 300457
- 折叠
摘要
Abstract
A simultaneous determination method for arsenic (As),lead (Pb)and cadmium (Cd)in cosmetics by inductively coupled plasma-optical emission spectrometry (ICP-OES)was established. The sample was digested by nitric acid - hydrogen peroxide under the assistance of microwave irradiation. Meanwhile,the conditions of ICP-OES were optimized. The method under optimized conditions shows good linearity with the mass concentrations of the three heavy metal ions in range of 0. 05 -1. 20 mg/L. The corresponding linear correlation coefficients for the heavy metals are all 0. 9998 with the spiked recoveries ranging within 90. 7% -108. 6%,and the relative standard deviation within 0. 44%-4. 59%(n =6 ). The limits of detection and quantification of As,Pb and Cd are 0. 63,0. 30,0. 015 mg/kg and 2. 1,1. 0,0. 05 mg/kg,respectively.关键词
化妆品/微波消解/电感耦合等离子体发射光谱法Key words
cosmetics/microwave digestion/inductively coupled plasma-optical emission spectrometry分类
化学工程引用本文复制引用
杨永超,孙永泽,张闯,闫婧,赵好力宝..ICP-OES法同时测定化妆品中砷、铅和镉[J].日用化学工业,2017,47(10):598-602,5.
