郑州大学学报(工学版)2017,Vol.38Issue(5):71-75,5.DOI:10.13705/j.issn.1671-6833.2017.05.019
功能离子液体催化CO2与环氧化合物的加成反应
The Cycloaddition Reaction of CO2 and Epoxy Compound Catalyzed by Hydroxyl and Carboxyl Functional Ionic Liquid
摘要
Abstract
A series of hydroxyl and carboxyl functionalized ionic liquids had been designed and used as catalyst for the cycloaddition reaction of CO2 with epoxy compound.Meanwhile,the relationship between catalyst structure and catalytic performance was studied.The influence of the ratio of epoxy propane and catalyst,reaction pressure,reaction temperature,reaction time on the properties of catalyst had been inspected using cycloaddition of propylene oxide and CO2 as model reaction.The repeatability of catalyst was discussed.关键词
离子液体/功能化/羟基/羧基/环加成反应/CO2/环氧化合物Key words
ionic liquids/functional/hydroxyl/carboxyl/cycloaddition/co2/epoxy compound分类
化学化工引用本文复制引用
吴晶敏,李伟杰..功能离子液体催化CO2与环氧化合物的加成反应[J].郑州大学学报(工学版),2017,38(5):71-75,5.基金项目
国家自然科学基金资助项目(21676071) (21676071)
河南省科技攻关计划资助项目(142102210614) (142102210614)