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壳聚糖基聚合物点荧光材料的合成及其对纸张的抗紫外老化性能

于淑娟 汪丰 罗振静 朱永飞

发光学报2017,Vol.38Issue(11):1443-1449,7.
发光学报2017,Vol.38Issue(11):1443-1449,7.DOI:10.3788/fgxb20173811.1443

壳聚糖基聚合物点荧光材料的合成及其对纸张的抗紫外老化性能

Synthesis of Chitosan-based Polymer Carbon Dots Fluorescent Materials and Their UV Aging Resistance Properties for Paper

于淑娟 1汪丰 1罗振静 1朱永飞1

作者信息

  • 1. 广西师范学院 化学与材料科学学院,广西 南宁 530001
  • 折叠

摘要

Abstract

Fluorescent materials P( CS-g-CA) Ds were prepared by hydrothermal method using chi-tosan, citric acid, and N-(2-hydroxyethyl) ethylenediamine as raw materials. It was found that graf-ted citric acid could significantly increase the quantum yield of chitosan polymer carbon dots. The P( CS-g-CA) Ds were characterized by infrared spectroscopy, ultraviolet spectroscopy ( UV) , X-ray powder diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, thermal de-composition and photoluminescence spectra. The fluorescence performance tests at different pH val-ues show that P( CS-g-CA) Ds have excellent stability in the pH range of 4 -12. The application performance of P( CS-g-CA) Ds in rice paper was studied by testing the carbonyl index and the vinyl index of the paper before and after UV aging. The results demonstrate that P(CS-g-CA)Ds have good UV aging resistance performance.

关键词

壳聚糖/柠檬酸/聚合物点荧光材料/紫外光老化

Key words

chitosan/citric acid/polymer carbon dots/UV aging

分类

化学化工

引用本文复制引用

于淑娟,汪丰,罗振静,朱永飞..壳聚糖基聚合物点荧光材料的合成及其对纸张的抗紫外老化性能[J].发光学报,2017,38(11):1443-1449,7.

基金项目

广西自然科学基金(2016GXNSFAA380203)资助项目 Supported by Natural Science Fund of Guangxi Province(2016GXNSFAA380203) (2016GXNSFAA380203)

发光学报

OA北大核心CSCDCSTPCD

1000-7032

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