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Ce改性Fe2O3催化剂对CO催化氧化的影响

陈然 高晓亚 王晶 陈柯臻 钟丽萍 雷艳秋 梅占强 罗永明

化工进展2017,Vol.36Issue(10):3737-3742,6.
化工进展2017,Vol.36Issue(10):3737-3742,6.DOI:10.16085/j.issn.1000-6613.2017-0090

Ce改性Fe2O3催化剂对CO催化氧化的影响

Effect of Ce addition on Fe2O3 catalyst towards CO catalytic oxidation

陈然 1高晓亚 1王晶 1陈柯臻 1钟丽萍 1雷艳秋 1梅占强 1罗永明1

作者信息

  • 1. 昆明理工大学环境科学与工程学院,云南昆明650500
  • 折叠

摘要

Abstract

A series of iron-ceria oxide catalysts were prepared by co-precipitation method and the effects of Ce adding into Fe2O3 on CO catalytic oxidation activity were investigated.Activity result shows that the addition of Ce increases the CO catalytic activity significantly,which can attain more than 90% CO conversion at ambient temperature and atomospheric pressure.Higher surface area and better redox ability than those of pure Fe2O3,and the formation of iron-ceria solid solution in the catalyst may be responsible for the increased catalytic activity.Additionally,different iron precursor has great influence on the CO catalytic oxidation.Sample that was prepared by using FeC13 as iron precursor shows the best catalytic performance.

关键词

催化/还原/氧化/一氧化碳

Key words

catalysis/reduction/oxidation/carbon monoxide

分类

资源环境

引用本文复制引用

陈然,高晓亚,王晶,陈柯臻,钟丽萍,雷艳秋,梅占强,罗永明..Ce改性Fe2O3催化剂对CO催化氧化的影响[J].化工进展,2017,36(10):3737-3742,6.

基金项目

国家自然科学基金项目(U1402233,21267011,21367015). (U1402233,21267011,21367015)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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