化工进展2017，Vol.36Issue(10)：3757-3764,8.DOI:10.16085/j.issn.1000-6613.2017-0129
乙烯-乙酸乙烯酯共聚物接枝聚合物的合成、表征及应用新进展
Recent advances in the synthesis, characterization and application of ethylene-vinyl acetate graft polymer
摘要
Abstract
In recent years,ethylene-vinyl acetate copolymer (EVA),due to its excellent low temperature resistance,oxidation resistance,environmental stress cracking resistance,corrosion resistance,etc.,has wide application prospect in a lot of areas.In order to endow it with new properties and functions and expand its applications,stuies of graft modification of EVA and related applications have drawn much attention recently.In this work,recent advances in the synthesis of EVA graft polymer via melt grafting,solution grafting and emulsion grafting was introduced firstly.Then,the grafting mechanism was analyzed using EVA-g-maleic anhydride polymer as an example.Subsequently,the characterization methods including instrument method and chemical titration and the applications of EVA graft polymer were summarized and reviewed.Finally,the advantages and disadvantages of the synthesis methods of EVA grafted polymer,characterization method and its application prospects are elaborated,and we pointed out that the solution grafting method is the future trend.Blending compatible materials,membrane materials and oil dewaxing materials will be the widely used areas in the future.关键词
乙烯-乙酸乙烯酯共聚物/接枝改性/接枝机理/聚合物/合成/表征Key words
ethylene-vinyl acetate copolymer/grafting modification/grafting mechanism/polymer/synthesis/characterization分类
化学化工引用本文复制引用
金世龙,郑斌茹,历娜,毛国梁,吴韦,崔崑..乙烯-乙酸乙烯酯共聚物接枝聚合物的合成、表征及应用新进展[J].化工进展,2017,36(10):3757-3764,8.基金项目
国家自然科学基金(51534004,U1362110,21374130)及上海市自然科学基金(14ZR1448700)项目. （51534004,U1362110,21374130）
