化工进展2017，Vol.36Issue(10)：3832-3849,18.DOI:10.16085/j.issn.1000-6613.2017-0195
以废气中的硫化氢开发含硫化学品的研究进展
Latest development of the sulfur-containing chemicals from hydrogen sulfide in waste gas
摘要
Abstract
High-quality sulfur-containing chemicals is still widely used in industries.And some of them are even facing a short supplying.Reusing and further processing for hydrogen sulfide from waste gas are not only economical beneficial but also environmentally friendly.This paper discussed 16 kinds of sulfur-containing compounds,which are classified further in eight sorts:inorganic sulfide,thiol,thioether,thiophenol,thioamide,sulfur-containing heterocycles,organic bisulfide,and high valence sulfur-containing organics.The basic physical and chemical properties,the main applications,and the market supplying of those compounds were presented.The status of research on the main synthetic methods both domestic and abroad was discussed with a focuses mainly on the industrial synthesis routes and the other synthesis routes based on the raw material hydrogen sulfide to develop the downstream products from recycled hydrogen sulfide rationally,an overall consideration should be conducted among the factors such as market positioning,technical manners and resource integration.Based on the current market,the methionine,polyphenylene sulfide are having promising market,which may be the priority for the future research.关键词
硫化氢/含硫化学品/合成路线/无机硫化物/硫醇/硫醚/硫酚/硫代酰胺/含硫杂环/有机二硫化物/高价硫有机物Key words
hydrogen sulfide/sulfur-containing chemicals/synthesis routes/inorganic sulfide/thiol/thioether/thiophenol/thioamide/sulfur-containing heterocycles/organic bisulfide/highvalencesulfur-containing organics分类
化学化工引用本文复制引用
张宏,李望,赵和平,王捷,陈经义,亢田礼..以废气中的硫化氢开发含硫化学品的研究进展[J].化工进展,2017,36(10):3832-3849,18.基金项目
安徽师范大学2014年博士科研启动基金项目(751442). （751442）
