燃料化学学报2017，Vol.45Issue(9)：1056-1063,8.
基于分子蒸馏的模拟生物油温和加氢研究
Mild hydrogenation of simulated bio-oil based on molecular distillation
摘要
Abstract
A mild hydrogenation of simulated bio-oil was carried out in a fixed-bed reactor.Based on the experimental results,300 ℃/4 MPa was chosen as an optimum condition for the mild hydrogenation,the simulated bio-oil was nearly completely converted.Besides,the liquid product selectivity achieved 85.0％ and its (H/C) eff was significantly promoted from 1.266 to 1.554.The liquid composition was greatly improved and a notable decrease of phenols and acids contents was observed.In this case,the product activity was significantly enhanced and then the subsequent catalytic cracking was favored.关键词
生物油/模化物/温和加氢/有效氢碳比Key words
bio-oil/model compounds/mild hydrogenation/effective hydrogen to carbon ratio分类
能源科技引用本文复制引用
陈军昊,卢亮,王树荣..基于分子蒸馏的模拟生物油温和加氢研究[J].燃料化学学报,2017,45(9):1056-1063,8.基金项目
The project was supported by the National Science and Technology Supporting Plan Through Contract (2015BAD15B06),the National Natural Science Foundation of China (51476142) and the National Basic Research Program of China (973 Program,2013CB228101).国家科技支撑计划项目(2015BAD15B06),国家自然科学基金面上项目(51476142)和国家重点基础研究发展规划(973计划,2013CB228101)资助 （2015BAD15B06）
