大连理工大学学报2017，Vol.57Issue(6)：551-556,6.DOI:10.7511/dllgxb201706001
掺硼金刚石中硼和石墨相含量对燃料电池阴极催化性能影响
Effect of doped boron and graphite phase content of boron-doped diamonds on catalytic performance of fuel cell cathode
摘要
Abstract
Boron-doped diamonds are good candidates as metal-free catalysts for the cathodic oxygen reduction reaction of fuel cells. The relationship between the content of doped boron and sp2 hybridized graphite phase in boron-doped diamonds with the oxygen reduction reaction potential and the current density is investigated.The results show that a certain amount of boron in boron-doped diamonds has a positive effect on the catalytic activity of the oxygen reduction reaction.With the increase of boron content,the oxygen reduction reaction activity increases first and then decreases while there is no significant change in the oxygen reduction reaction potential.Catalytic sites and step atomic density are considered to play a synthetic role.Moreover,sp2 hybridized graphite phase can make the potential of the oxygen reduction reaction shift toward more positive.关键词
氧还原反应/掺硼金刚石/催化/燃料电池Key words
oxygen reduction reaction/boron-doped diamond/catalysis/fuel cell分类
信息技术与安全科学引用本文复制引用
王蕾,索妮,张贵锋,吴爱民,黄昊..掺硼金刚石中硼和石墨相含量对燃料电池阴极催化性能影响[J].大连理工大学学报,2017,57(6):551-556,6.基金项目
国家重点研发计划资助项目(2016YFB0101206) （2016YFB0101206）
常州科技支撑计划(工业)资助项目(CE20160022) （工业）
常州市企业领军型创新人才引进培 育 计 划 资 助 项 目 (CQ20153002 ) （CQ20153002 ）
中 央 高 校 基 本 科 研 业 务 费 专 项 资 金 资 助 项 目 (DUT16LAB03, DUT15LAB05). （DUT16LAB03, DUT15LAB05）
