化工学报2017，Vol.68Issue(11)：4398-4406,9.DOI:10.11949/j.issn.0438-1157.20170325
钯/纳米石墨片复合材料的制备及其对甲醇的电催化性能
Facile preparation of Pd/graphite nanoplate composites for electrocatalytic oxidation of methanol
摘要
Abstract
Graphite nanoplates were prepared by combining the modified Hummers and mechanical stripping method. Pd nanoparticles supported on graphite nanoplates were successfully synthesized by a simple one-step reduction method with sodium borohydride as the reducing agent. The results show that this new method for the preparation of graphite nanoplates is simple, fast and efficient. Pd nanoparticles with an average size of 11.5 nm are well dispersed on the surface of graphite nanoplates. The composite materials exhibited excellent catalytic activity and poison resistance for the electro-oxidation of methanol in alkaline medium, superior to the Pd supported on the reduced graphene oxide prepared by traditional modified Hummers method and commercial carbon black Vulcan XC-72, respectively.关键词
纳米材料/电化学/燃料电池/阳极催化剂/甲醇电氧化Key words
nanomaterials/electrochemistry/fuel cells/anode catalyst/methanol electrochemical oxidation分类
化学化工引用本文复制引用
朱瑞芝,周扬,夏甜甜,刘志华,王昆淼,常钢,蔡志伟,操日兵,何云斌..钯/纳米石墨片复合材料的制备及其对甲醇的电催化性能[J].化工学报,2017,68(11):4398-4406,9.基金项目
云南省烟草化学重点实验室开放基金项目(2016539200340109) （2016539200340109）
武汉市晨光计划项目(2014072704011252). supported by the Key Laboratory of Tobacco Chemistry Foundation of Yunnan Province (2016539200340109) and the Wuhan Youth Science and Technology Morning Program (2014072704011252). （2014072704011252）
