燃料化学学报2017,Vol.45Issue(11):1289-1295,7.
炭化温度对红柳林煤温和液化-炭化耦合转化产物的影响
Effects of carbonization temperature on the products from integrated mild-liquefaction and carbonization process of Hongliulin coal
摘要
Abstract
The integrated mild-liquefaction and carbonization experiments of Hongliulin coal were conducted at 430-600℃, and distributions and physico-chemical properties of the obtained products were investigated. The results show that the yields of semi-cokes, organic liquid products and n-hexane soluble organic products were up to 40. 64%-53. 02%, 30. 89%-36. 98% and 29. 74%-33. 28%, respectively. The increasing carbonization temperature in the relatively low temperature range was favorable for the elevated yield of n-hexane soluble organic products, while at relatively high temperature presenting an opposite one. The semi-cokes obtained at 430℃ presented a strong caking property, while those at 550℃ showed no caking property, and the content of their volatile matters decreased to about 10%. It is suggested that the produced semi-coke could be directionally utilized as blending coal in coking or smokeless fuel by adjusting carbonization temperature.关键词
煤/温和液化/炭化/半焦/液相产物Key words
coal/mild-liquefaction/carbonization/semi-coke/liquid phase products分类
化学化工引用本文复制引用
周旭辉,吴诗勇,尤全,黄胜,吴幼青,高晋生,郑化安,闵小建,尚建选..炭化温度对红柳林煤温和液化-炭化耦合转化产物的影响[J].燃料化学学报,2017,45(11):1289-1295,7.基金项目
The project was supported by the National Natural Science Foundation of China (21476079, 21476080) and the Fundamental Research Funds for the Central Universities (WB1414014).国家自然科学基金(21476079, 21476080)和中央高校基本业务费(WB1414014)资助 (21476079, 21476080)