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阳离子聚丙烯酰胺絮凝回收利用SAPO-34分子筛母液

狄春雨 李志宏 何祖光 窦涛 范彬彬

太原理工大学学报2017,Vol.48Issue(6):887-892,6.
太原理工大学学报2017,Vol.48Issue(6):887-892,6.DOI:10.16355/j.cnki.issn1007-9432tyut.2017.06.002

阳离子聚丙烯酰胺絮凝回收利用SAPO-34分子筛母液

Recycling of SAPO-34 Molecular Sieve Mother Liquor by Using Cationic Polyacrylamide Flocculant

狄春雨 1李志宏 1何祖光 1窦涛 2范彬彬1

作者信息

  • 1. 太原理工大学化学化工学院,太原030024
  • 2. 中国石油大学(北京)化工学院CNPC催化重点实验室,北京102249
  • 折叠

摘要

Abstract

Effective components from the crystallized mother liquor of zeolite catalysts were recovered by cationic polyacrylamide and dilute hydrochloric acid flocculation method,dried and ground into powder.After adding to the components a certain amount of silicon aluminum and other raw materials,hierarchical SAPO-34 molecular sieve with sheet stacking was synthesized by dry gel conversion method.The results show that mesoporous SAPO-34 molecular sieve gave a pore volume as high as 0.40 cm3/g,a catalytic life time of 200 min and a selectivity of light olefin (ethylene + propylene)of 87% for MTO reaction.The synthesis approach turns out to be sim-ple,economical and efficient.

关键词

聚丙烯酰胺/晶化母液/SAPO-34/干胶转化/多级孔/MTO

Key words

plyacrylamide/mother liquor/SAPO-34/DGC/hierarchical/MTO

分类

化学化工

引用本文复制引用

狄春雨,李志宏,何祖光,窦涛,范彬彬..阳离子聚丙烯酰胺絮凝回收利用SAPO-34分子筛母液[J].太原理工大学学报,2017,48(6):887-892,6.

基金项目

国家自然科学基金资助项目(20973123) (20973123)

山西省火炬计划资助项目(2014061002-01) (2014061002-01)

太原理工大学学报

OA北大核心CSTPCD

1007-9432

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