硅酸盐学报2017，Vol.45Issue(11)：1548-1554,7.DOI:10.14062/j.issn.0454-5648.2017.11.02
固体氧化物燃料电池中的陶瓷材料
Ceramic Materials for Solid Oxide Fuel Cell
摘要
Abstract
Solid oxide fuel cell (SOFC) is known as a ceramic fuel cell. The key components including electrolyte, cathode and anode are ceramic materials. The dense electrolyte film requires a pure oxygen ion conductivity. In general, the oxygen ion conductivity is mainly derived from the oxygen vacancy in oxide materials by doping lower valence metallic ions. Fluorite structured Y2O3 stabilized ZrO2 (YSZ) and Sc2O3 stabilized ZrO2 (ScSZ) are the main electrolyte materials for industrial application. The doped CeO2,δ-Bi2O3 and doped LaGaO3 perovskite, with a higher oxygen ion conductivity, have a potential application for SOFC at a lower temperature. The electrodes are porous ceramic materials with oxygen ion and electron conductivity. Ni-YSZ cermet has been used in industries due to its high electrochemical performance. The perovskite materials with a mixed ionic and electronic conductivity (MIEC) have attracted considerable attention because of their potential applications in SOFC under hydrocarbon fuels. Doped LaMnO3-YSZ composite ceramic is a widely used cathode material for high-temperature SOFC, having a high electrochemical performance and a good stability in long-term operation. While the doped LaFeO3, especially La0.6Sr0.4Co0.2Fe0.8O3, is used in intermediate-temperature SOFC, also showing good electrochemical activity and stability. Moreover, optimizing the composition and structure of cathode material remains a research focus for the development of SOFC.关键词
固体氧化物燃料电池/氧离子导体/混合离子电子导体/金属陶瓷阳极/钙钛矿电极Key words
solid oxide fuel cell/oxide-ion conductor/mixed ion electronic conductivity/cermet materials/perovskite electrode分类
化学化工引用本文复制引用
韩敏芳,张永亮..固体氧化物燃料电池中的陶瓷材料[J].硅酸盐学报,2017,45(11):1548-1554,7.基金项目
国家重大研发计划(2017YFB0601903) （2017YFB0601903）
北京市百名领军人才项目(Z151100000315031) （Z151100000315031）
山西省科技厅项目(MD2014-08) （MD2014-08）
东莞市引进创新科研团队(201460720100025) （201460720100025）
清华大学自主科研计划(2015THZ0). （2015THZ0）
