表面技术2017，Vol.46Issue(12)：62-70,9.DOI:10.16490/j.cnki.issn.1001-3660.2017.12.012
新型环保海洋防污材料研究进展
Development of Novel Environment-friendly Antifouling Materials
摘要
Abstract
Development history and antifouling mechanisms of marine antifouling materials were briefly reviewed, and the latest research progress of novel environmental-friendly antifouling materials was presented. After tributyltin-containing self-polishing copolymer (SPC) coatings were prohibited, copper, zinc and silyl acrylate polymers-based coatings have been widely used. In order to further improve the antifouling properties and environmental protection performance, research is now focusing on grafted antifouling functional group materials, biodegradable macromolecule-based antifouling materials, main chain degradable self-polishing antifouling materials, anti-drag antifouling materials and biomimetic antifouling materials. Grafting methods and antifouling effects of several antifouling functional groups such as Schiff base, glyphosate and benziso-thiazolinone were introduced. It was pointed out that such methods could improve utilization ratio of antifoulant and gain a steady release rate of antifoulant. However, such problems as reduced antifouling capacity due to grafting modification and complex synthesis process should be solved to apply such methods. Moreover, structure and synthesis methods of biodegradable macromolecule-based antifouling materials, especially main chain degradable and side chain hydrolysable were introduced em-phatically. As these hydrolysable/degradable resins exhibited good mechanical properties and hydrolysis controlled performance, the anti-fouling coatings as-prepared could release antifoulant steadily even in static state. Therefore, the resins could be used to develop novel main chain degradable self-polishing antifouling coatings, so as to improve durability of the coatings in static state, the resins had good application prospects. Methods of reducing surface roughness of the antifouling coatings after hydro-lysis such as macromolecule resin modification were introduced as well. Such anti-fouling coatings exhibited good anti-drag re-sistance. Finally, the progress of biomimetic antifouling materials was introduced.关键词
海洋防污/自抛光/防污功能基团/主链降解/减阻/仿生材料Key words
marine antifouling/self-polishing/antifouling functional groups/main-chain degradation/drag reduction/bio-mimetic materials分类
建筑与水利引用本文复制引用
叶章基,陈珊珊,马春风,吴建华,张广照..新型环保海洋防污材料研究进展[J].表面技术,2017,46(12):62-70,9.基金项目
"十三五"国家海洋经济创新发展示范项目(16CZB023SF12) （16CZB023SF12）
海洋公益科研专项(201305016) （201305016）
福建省海洋生物资源开发利用协同创新中心产学研基金(FJMBIO1504)Supported by the "13th Five-year" Marine Economy Innovative Development Demonstrative Project of China (16CZB023SF12), the Public Science and Technology Research Funds Project of Ocean of China (201305016) and the Research Funds Project of Fujian Collaborative Innovation Center for Exploitation and Utilization of Marine Biological Resource (FJMBIO1504) （FJMBIO1504）
