华东理工大学学报（自然科学版）2017，Vol.43Issue(5)：620-626,7.DOI:10.14135/j.cnki.1006-3080.2017.05.004
酯侧链结构对丙烯酸酯聚合物与天然乳胶共混相容性的影响
Effect of Ester Side Chain Structure on the Compatibility of Acrylic Polymer Latex and Natural Rubber
摘要
Abstract
Acrylic polymers with different ester side chains were synthesized by emulsion polymerization and then blended with natural rubber (NR) latex with various mass fractions (w=5％,10％ and 15％) to study the effect of ester side chain structure on the compatibility of acrylic polymer latex and natural rubber.The results showed that with the dosage of 10％ the latex film modified by polymer with the largest number of alkyl groups and the longest ester side chain showed the largest tensile strength,tear strength,hardness and elongation at break but the minimum tension set.Upon increasing amount of alkyl groups and length of ester side chain on the polymer,the surface of blend film became even and smooth,the fracture of the films became dense and precipitate free and the glass temperature of blend films increased,suggesting the continuous increase in the mutual diffusion between two phases of the blends.Finally,a modified film material with excellent properties was obtained.关键词
天然乳胶/酯侧链/共混相容性Key words
natural rubber/ester side chain/compatibility分类
化学化工引用本文复制引用
郑钊君,田晓慧,孙金煜,冯屏,赵伟如..酯侧链结构对丙烯酸酯聚合物与天然乳胶共混相容性的影响[J].华东理工大学学报（自然科学版）,2017,43(5):620-626,7.基金项目
国家高技术研究发展项目(2009AA035002) （2009AA035002）
上海市重点学科(B502)和重点实验室项目(08DZ2230500) （B502）
中央高校基本科研业务费(22A201514002) （22A201514002）
