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强还原过程对设施菜地土壤重金属形态转化的影响

孙延琛 曾祥峰 杨立琼 石亚楠 陈希娟 庄杰

应用生态学报2017,Vol.28Issue(11):3759-3766,8.
应用生态学报2017,Vol.28Issue(11):3759-3766,8.DOI:10.13287/j.1001-9332.201711.032

强还原过程对设施菜地土壤重金属形态转化的影响

Effects of strong reductive process on transformation of heavy metals in protected vegetable soil

孙延琛 1曾祥峰 2杨立琼 1石亚楠 1陈希娟 1庄杰1

作者信息

  • 1. 中国科学院沈阳应用生态研究所污染生态与环境工程重点实验室,沈阳110016
  • 2. 中国科学院大学,北京100049
  • 折叠

摘要

Abstract

The application of sewage and manure in protected vegetable cultivation can induce the occurrence of heavy metals contamination.The present research studied the transformation of heavy metals (Cd,Cu,Pb and Zn) by incubating contaminated protected soil with maize straw and then leaching.The results showed that soil pH was significantly decreased,being more evident in maize straw treatment;soil Eh dropped quickly below-280 mV.Maize straw treatment promoted the activation of Cd,Cu,Pb and Zn from soil,and the total percent of oxidizable fraction and residual fraction of Cd,Cu,Pb and Zn declined at 9th day;the amount of Cd,Cu,Pb and Zn in soil reduced 18.1%,19.0%,16.1% and 15.7% at 15th day,respectively.Compared to control,maize straw treatment could increase the concentrations of dissolved Cd and Zn,but Cu decreased.The concentration of colloidal-bound Cd and Pb increased,Cu decreased and no significant change occurred in Zn in maize straw treatment.Strong reductive approach could activate heavy metals in protected vegetable soil,increase the risk of heavy metals accumulation in vegetables,and possibly cause water pollution accompanied with soil water mobilization.

关键词

设施菜地/强还原/重金属/形态转化

Key words

protected vegetable soil/strong reductive/heavy metals/speciation transformation

引用本文复制引用

孙延琛,曾祥峰,杨立琼,石亚楠,陈希娟,庄杰..强还原过程对设施菜地土壤重金属形态转化的影响[J].应用生态学报,2017,28(11):3759-3766,8.

基金项目

本文由国家水体污染控制与治理科技重大专项(2015ZX07202-012)和天津市水资源与水环境重点实验室开放基金资助 This work was supported by Major Project of the National Water Pollution Control and Treatment Science and Technology (2015ZX07202-012) and the Opening Fund of Tianjin Key Laboratory of Water Resources and Environment. (2015ZX07202-012)

应用生态学报

OA北大核心CSCDCSTPCD

1001-9332

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