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石墨烯负载硫化锌/硫化铜异质结的制备及光催化性能

曾斌 陈小华 汪次荣

材料工程2017,Vol.45Issue(12):99-105,7.
材料工程2017,Vol.45Issue(12):99-105,7.DOI:10.11868/j.issn.1001-4381.2015.001112

石墨烯负载硫化锌/硫化铜异质结的制备及光催化性能

Synthesis and Photocatalytic Properties of Reduced Graphene Oxides Loaded-nano ZnS/CuS Heterostructures

曾斌 1陈小华 2汪次荣2

作者信息

  • 1. 湖南文理学院机械工程学院,湖南常德415000
  • 2. 湖南大学材料科学与工程学院 ,长沙410082
  • 折叠

摘要

Abstract

The reduced graphene oxides(rGO) loaded-nano ZnS nanoparticles were fabricated by micro-wave heating method and by ion exchanged reaction reduced graphene oxides(rGO) loaded-nano ZnS/CuS heterostructures were obtained .The structure ,morphology were characterized viascanning elec-tron microscopy (SEM ) , transmission electron microscopy (TEM ) and X-ray diffraction pattern (XRD) .The effect of the mass fraction of graphene oxides ,sulfur source and microwave heating time on the morphology and photocatalyitc performance were discussed .The results show that graphene uniformly loaded-nano ZnS/CuS heterostructures are obtained on the condition of graphene mass frac-tion of 10% ,thioacetamide acting as sulfur source ,microwave heating time is 30min .rGO-loaded nano ZnS/CuS heterostructures nanoparticles enhance photocatalytic performance with 81 .2% decom-position of MO in 150min under visible light ,demonstrating the excellent photocatalytic performance . The high visible photocatalytic performances are attributed to photoinduced interfacial charge transfer in the nano heterostructures and their further separation and transfer by rGO .

关键词

还原氧化石墨烯/异质结/光催化性能

Key words

reduced graphene oxide/heterostructure/photocatalytic performance

分类

通用工业技术

引用本文复制引用

曾斌,陈小华,汪次荣..石墨烯负载硫化锌/硫化铜异质结的制备及光催化性能[J].材料工程,2017,45(12):99-105,7.

基金项目

国家自然科学基金资助项目(51272073 ) (51272073 )

湖南省科学技术厅科技计划项目资助(2014GK3094 ) (2014GK3094 )

湖南省教育厅青年项目资助(15B158) (15B158)

湖南省重点建设学科资助(XJF[2011]76) (XJF[2011]76)

材料工程

OA北大核心CSCDCSTPCD

1001-4381

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