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金属取代CHA型硅铝酸盐分子筛的水热合成

刘素花 马岩 董卉 赵存 宋宇

大连工业大学学报2017,Vol.36Issue(6):440-443,4.
大连工业大学学报2017,Vol.36Issue(6):440-443,4.

金属取代CHA型硅铝酸盐分子筛的水热合成

Hydrothermal synthesis of metal substituted CHA aluminosilicate molecular sieves

刘素花 1马岩 1董卉 1赵存 1宋宇1

作者信息

  • 1. 大连工业大学 纺织与材料工程学院 ,辽宁 大连 116034
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摘要

Abstract

The aluminosilicate zeolite SAPO-34 with CHA topology was synthetized by hydrothermal synthesis method using aluminum isopropoxide as aluminum source ,phosphoric acid as phosphorus source ,TEOS as silicon source and triethylamine as the template.The effects of reaction conditions such as the metal kinds and contents on zeolite crystal synthesis and crystal morphology were studied. The synthesized zeolite was characterized by XRD ,SEM and TG-DTA methods.The results showed that doping Co was benefit to the generation of SAPO-34 ,which could improve the crystallinity and decrease the crystal size. The amount of Co-doped could affect the morphology.Doping a small amount of metal Ti is beneficial to the formation of target products.

关键词

分子筛/金属取代/水热合成

Key words

zeolite/metal substitution/hydrothermal synthesis

分类

化学化工

引用本文复制引用

刘素花,马岩,董卉,赵存,宋宇..金属取代CHA型硅铝酸盐分子筛的水热合成[J].大连工业大学学报,2017,36(6):440-443,4.

大连工业大学学报

OA北大核心CSTPCD

1674-1404

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