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双金属位催化剂Ag-Ni/g-C3N4可见光催化降解亚甲基蓝

郑小刚 杜京城 付孝锦 由耀辉 宋玉春 李子黎 刘勇

硅酸盐学报2018,Vol.46Issue(1):85-92,8.
硅酸盐学报2018,Vol.46Issue(1):85-92,8.DOI:10.14062/j.issn.0454-5648.2018.01.12

双金属位催化剂Ag-Ni/g-C3N4可见光催化降解亚甲基蓝

Carbon Nitride Bimetallic Ag-Ni/g-C3N4 Catalysts for Photocatalytic Degradation of Methylene Blue under Visible-light Irradiation

郑小刚 1杜京城 1付孝锦 1由耀辉 1宋玉春 1李子黎 1刘勇1

作者信息

  • 1. 内江师范学院化学化工学院,四川 内江,641100
  • 折叠

摘要

Abstract

The supported bimetallic Ag-Ni/g-C3N4 photocatalysts were generated by an in-situ reduction route, and the photocatalytic degradation of methylene blue under visible light illumination was investigated. The results indicate that the bimetallic Ag-Ni/g-C3N4 sample presents a better photocatalytic activity for methylene blue, compared to Ag/g-C3N4 and Ni/g-C3N4 samples. At the total loading mass of metal particles of 4.0%, the photocatalyst Ag(2)-Ni(2)/g-C3N4 sample with Ag/Ni mass ratio of 1:1 exhibits a superior degradation activity, and slightly deactivates after seven times. It can be ascribed to the synergetic effect between metallic Ag and Ni, which can greatly enhance the transfer rate of photo-induced carriers and effectively separate the photo-generated electron-hole pairs.

关键词

氮化碳/银-镍负载/协同效应/亚甲基蓝/光催化活性

Key words

carbon nitride/silver-nickel loading/synergetic effect/methylene blue/photocatalytic activity

分类

化学化工

引用本文复制引用

郑小刚,杜京城,付孝锦,由耀辉,宋玉春,李子黎,刘勇..双金属位催化剂Ag-Ni/g-C3N4可见光催化降解亚甲基蓝[J].硅酸盐学报,2018,46(1):85-92,8.

基金项目

国家自然基金青年基金(21506103)项目. (21506103)

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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