合成材料老化与应用2017，Vol.46Issue(6)：5-7,37,4.
含羧基丙烯酸酯橡胶的合成与表征
Synthesis and Characterization of Carboxyl-containing Acrylate Rubber
摘要
Abstract
Carboxyl-containing acrylate rubber was synthesized with ethyl acrylate and butyl acrylate as main monomers,and acrylic acid as crosslinking-point monomer via semi-continuous seeded emulsion polymerization method. The effect of the amount of acrylic acid on the monomer conversion in emulsion polymerization was stud-ied,the structure of carboxyl-containing acrylate rubber was characterized with FT-IR and DSC,and the mechani-cal properties of the vulcanized rubber were also measured. The results showed that the addition of acrylic acid was beneficial for the increase of monomer conversion,and the glass transition temperatures of the obtained acry-late rubber increased with the amount of acrylic acid increasing. 1 # vulcanizing agent and di-o-tolylguanidine could effectively accelerate the vulcanization of carboxyl-containing acrylate rubber. When the amount of acrylic acid was 4%, the tensile strength and break at elongation of the vulcanized rubber reached to 5. 8 MPa and 606%,respectively.关键词
丙烯酸酯橡胶/丙烯酸/乳液聚合/力学性能Key words
acrylate rubber/acrylic acid/emulsion polymerization/mechanical properties分类
化学化工引用本文复制引用
王惊,李红强,赖学军,曾幸荣,石建伟,韩泽明,潘杰辉..含羧基丙烯酸酯橡胶的合成与表征[J].合成材料老化与应用,2017,46(6):5-7,37,4.基金项目
广州市科技计划项目产学研协同创新重大专项(201604010028) （201604010028）
