化工环保2017，Vol.37Issue(4)：460-465,6.DOI:10.3969/j.issn.1006-1878.2017.04.016
Zr掺杂TiO2介孔材料光催化降解头孢氨苄
Photocatalytic degradation of cefalexin by Zr-doped TiO2 mesoporous material
摘要
Abstract
Zr-doped TiO2 (Zr-TiO2) was prepared by solid-phase synthesis for photocatalytic degradation of cefalexin in solution and characterized by XRD.The optimum reaction conditions were confirmed by single factor experiments and orthogonal experiments.The results showed that:The Zr-TiO2 was anatase type mesoporous material with about 8.12 nm of pore size;The factors affecting cefalexin removal were arrayed in descending order with irradiation time,Zr-TiO2 amount and initial cefalexin mass concentration;Under the optimum reaction conditions of Zr-TiO2 amount 1.5 g/L,initial cefalexin mass concentration 10 m/L,solution pH 7.0 and irradiation time 1.5 h (300 W UV),the cefalexin removal rate was up to 99.46％;In addition,the photocatalyst had good reuse performance.关键词
固相合成/锆改性二氧化钛/头孢氨苄/光催化降解/正交实验Key words
solid-phase synthesis/Zr-doped TiO2/cefalexin/photocatalytic degradation/orthogonal test分类
资源环境引用本文复制引用
胡秀虹,汤承浩,吴林冬,王翔,刘少友..Zr掺杂TiO2介孔材料光催化降解头孢氨苄[J].化工环保,2017,37(4):460-465,6.基金项目
贵州省教育厅自然科学基金研究青年项目(黔教合KY字[2014] 311) （黔教合KY字[2014] 311）
贵州省教育质量提升工程项目(黔教合KY字[2014] 228) （黔教合KY字[2014] 228）
贵州省普通高等学校微介孔纳米材料制备与应用特色重点实验室项目(黔教科KY字[2012] 014). （黔教科KY字[2012] 014）
