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酸化凹凸棒石的制备及其对苯胺的吸附性能

关媛 王少莽 易广 陈璐 吴鑫泉 陆武 翁彭

常州大学学报(自然科学版)2017,Vol.29Issue(6):15-25,11.
常州大学学报(自然科学版)2017,Vol.29Issue(6):15-25,11.DOI:10.3969/j.issn.2095-0411.2017.06.003

酸化凹凸棒石的制备及其对苯胺的吸附性能

Preparation of Acidified Palygorskite and Its Adsorption Performance for Aniline

关媛 1王少莽 2易广 1陈璐 1吴鑫泉 1陆武 2翁彭2

作者信息

  • 1. 常州大学 石油化工学院,江苏 常州 213164
  • 2. 常州大学 环境与安全工程学院,江苏 常州 213164
  • 折叠

摘要

Abstract

Natural palygorskite was acidified with different concentration of hydrochloric acid.The acid-ified palygorskite was characterized by XRD,SEM,BET,FTIR and ZATA potential.Under different process conditions,the adsorption performance of acidified palygorskite treated with different concen-tration of hydrochloric acid,was evaluated by removal of aniline in water.When the activation concen-tration of hydrochloric acid was 6mol·L-1 ,the pH value of the aniline solution was 6,the initial mass concentration of aniline was 50mg·L-1 ,the amount of adsorbent was 0.5g,the temperature was 30℃,the adsorption time was 240min,the acidified palygorskite could acquire better adsorption activity and remove more than 75.2% of aniline.In addition,the adsorption behavior of aniline over a-cidified palygorskite was more suitable to be described by pseudo-second-order kinetic model.

关键词

凹凸棒石/酸化改性/吸附/苯胺/假二级动力学模型

Key words

palygorskite/acidification/adsorption/aniline/pseudo-second-order kinetic model

分类

化学化工

引用本文复制引用

关媛,王少莽,易广,陈璐,吴鑫泉,陆武,翁彭..酸化凹凸棒石的制备及其对苯胺的吸附性能[J].常州大学学报(自然科学版),2017,29(6):15-25,11.

基金项目

中国博士后基金面上项目(2017M611784) (2017M611784)

江苏省自然科学基金面上项目(BK20161277) (BK20161277)

江苏省高校自然科学基金面上项目(16KJB610002). (16KJB610002)

常州大学学报(自然科学版)

2095-0411

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