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神府烟煤焦与城市固体废弃物水热炭焦共气化反应特性的实验研究

何清 卫俊涛 龚岩 丁路 于广锁

燃料化学学报2017,Vol.45Issue(10):1191-1199,9.
燃料化学学报2017,Vol.45Issue(10):1191-1199,9.

神府烟煤焦与城市固体废弃物水热炭焦共气化反应特性的实验研究

Experimental study on co-gasification reactivity of Shenfu bituminous coal char and MSW-based hydrochar

何清 1卫俊涛 1龚岩 1丁路 2于广锁1

作者信息

  • 1. 华东理工大学 煤气化及能源化工教育部重点实验室,上海 200237
  • 2. 东京工业大学 环境社会理工学院,东京 1528550
  • 折叠

摘要

Abstract

The influences of gasification temperature (800-950℃) and blending ratio (3∶1,1∶1,1∶3) on the isothermal CO2 co-gasification reactivities of Shenfu bituminous coal char (SF char) and HTC char were investigated using an atmospheric thermogravimetric analyzer (TGA).Moreover,the activation energy of char gasification and its influence factors were explored.The results show that the greater surface area and the higher ash content are the main reasons for the high gasification reactivity of HTC char.The reactivities of mixtures with low HTC char proportion are more sensitive to temperature at low temperature range.The activation energy increases with the increase of carbon conversion,and the activation energy correlates well with the blending ratio and the molar ratio of active (K+Na)/Ca in the char.

关键词

共气化//水热炭/反应特性/活化能

Key words

co-gasification/coal/hydrochar/reactivity/activation energy

分类

化学化工

引用本文复制引用

何清,卫俊涛,龚岩,丁路,于广锁..神府烟煤焦与城市固体废弃物水热炭焦共气化反应特性的实验研究[J].燃料化学学报,2017,45(10):1191-1199,9.

基金项目

The research was supported by the National Nature Science Foundation of China (21676091,21376081) and the Fundamental Research Funds for the Central Universities (222201717004).国家自然科学基金(21676091,21376081)和中央高校基本科研业务费(222201717004)资助 (21676091,21376081)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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