燃料化学学报2017，Vol.45Issue(12)：1417-1423,7.
燃烧反应过程中胜利脱灰褐煤微结构演变特性研究
Microstructure evolution characteristics of Shengli lignite during combustion process
摘要
Abstract
The combustion of Shengli lignite demineralized with hydrochloric acid was carried and residues from different reaction conditions were obtained. The microstructural properties of the lignite and residues were examined by FT-IR, XRD, XPS and Raman, respectively. The results indicate that aliphatic functional groups were consumed during combustion, while oxygen-containing groups and aromatic structure were consumed and generated alternatively. The proportion of C-C/C-H structure decreased after increasing, while the content of carbon-oxygen structure was increased following decrease. The aromaticity of residues increased and ID/IG increased before decrease, while IS/IG decreased before increase. This indicated that graphitization transformation degree of lignite obviously increased during combustion, especially in the late stage of reaction.关键词
胜利褐煤/煤自燃/未反应残留物/结构特性Key words
Shengli lignite/coal spontaneous combustion/unreacted residues/structure characteristics分类
化学化工引用本文复制引用
宋银敏,李娜,班延鹏,滕英跃,智科端,何润霞,周华从,刘全生..燃烧反应过程中胜利脱灰褐煤微结构演变特性研究[J].燃料化学学报,2017,45(12):1417-1423,7.基金项目
The project was supported by the National Natural Science Foundation of China (21676149, 21606134, 21566029, 21566028, 21266017, 21766023), Natural Science Foundation of Inner Mongolia (2014MS0220, 2015BS0206, 2016BS0204, 2017MS0201), Plan of Scientific and Technology of Inner Mongolia, Incentive Fund for the Scientific and Technology Innovation Program of Inner Mongolia and Major Basic Research Open Programs of Inner Mongolia.国家自然科学基金(21676149, 21606134, 21566029, 21566028, 21266017, 21766023),内蒙古自然科学基金(2014MS0220, 2015BS0206, 2016BS0204, 2017MS0201), 内蒙古科技计划,内蒙古科技引导奖励基金和内蒙古自治区重大基础研究开放课题资助 （21676149, 21606134, 21566029, 21566028, 21266017, 21766023）
