| 注册
首页|期刊导航|燃料化学学报|载体对负载型NiSn催化剂丙烷脱氢性能的影响

载体对负载型NiSn催化剂丙烷脱氢性能的影响

张焕玲 王国玮 山红红 李春义

燃料化学学报2017,Vol.45Issue(12):1529-1536,8.
燃料化学学报2017,Vol.45Issue(12):1529-1536,8.

载体对负载型NiSn催化剂丙烷脱氢性能的影响

Propane dehydrogenation over NiSn-based catalysts

张焕玲 1王国玮 1山红红 1李春义1

作者信息

  • 1. 中国石油大学(华东) 重质油国家重点实验室,山东 青岛 266580
  • 折叠

摘要

Abstract

In this paper, we studied the effects of supports, such as SiO2 , MgO, Al2 O3 and MgAl2 O4 , on the performance of supported NiSn catalyst for propane dehydrogenation. NH3 temperature-programmed desorption, H2 temperature-programmed reduction were applied for the characterization of the catalysts. The results show that SiO2 with large specific surface area and large pore size can achieve good contact between catalyst and reactants, leading to a high content of Ni2. 67 Sn2 alloy and a reduced diffusion resistance, In addition, their weak acid improve dehydrogenation activity and propene selectivity.

关键词

丙烷脱氢/NiSn催化剂/载体

Key words

propane dehydrogenation/NiSn-based catalysts/support

分类

化学化工

引用本文复制引用

张焕玲,王国玮,山红红,李春义..载体对负载型NiSn催化剂丙烷脱氢性能的影响[J].燃料化学学报,2017,45(12):1529-1536,8.

基金项目

The project was supported by the National Natural Science Foundation of China(21606257,U1362201).国家自然科学基金(21606257,U1362201)资助 (21606257,U1362201)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

访问量0
|
下载量0
段落导航相关论文