山西大学学报（自然科学版）2017，Vol.40Issue(4)：838-845,8.DOI:10.13451/j.cnki.shanxi.univ(nat.sci.).2017.04.026
钢渣催化剂提升直接碳燃料电池性能研究
Steel-slag Catalysts for Improving the Performance of Direct Carbon Fuel Cells
摘要
Abstract
The CO2 gasification reaction of solid carbon (C+CO2 =2CO),i.e.the reverse Boudouard reaction,is one of the key reactions determining the performance of solid oxide direct carbon fuel cells (SODCFC).Based on the comparison study of the reverse Boudouard reactivity of coal char and that loaded with acid-activated steel-slag catalyst,the electrochemical performance of DC-SOFC fuelled with the two fuels was investigated comparatively.The results showed that the acid-activated steel-slag catalyst reduced 240℃C of the initial temperature of the reverse Boudouard reaction of coal char,and increased 4 times of the CO producing rate.For the electrochemical performance,the acid-activated steel-slag catalyst enhanced the peak power density of the cell at 850℃C from 67.4 mW cm-2 to 200.4 mW · cm-2,and improved the fuel availability from 41.5％ to 79.6％.关键词
固体氧化物直接碳燃料电池/钢渣催化剂/酸法活化/逆Boudouard反应/电化学性能Key words
solid oxide direct carbon fuel cell/steel-slag catalyst/acid activation/reverse Boudouard reaction/electrochemical performance分类
化学化工引用本文复制引用
付艺丽,薛晓婷,焦勇,安文汀,邵宗平,李思殿..钢渣催化剂提升直接碳燃料电池性能研究[J].山西大学学报（自然科学版）,2017,40(4):838-845,8.基金项目
山西省自然科学基金(201601D102014) （201601D102014）
山西省科技攻关项目(20150313003-3) （20150313003-3）
