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臭氧改性对活性炭表面性能的影响及在卷烟中的应用

余其昌 黄菲 陈森林 黄奕瑕 孔浩辉 肖静 李忠

烟草科技2017,Vol.50Issue(11):27-32,38,7.
烟草科技2017,Vol.50Issue(11):27-32,38,7.

臭氧改性对活性炭表面性能的影响及在卷烟中的应用

Effects of ozone modification on surface properties of activated carbon and its application to cigarette filter

余其昌 1黄菲 1陈森林 1黄奕瑕 2孔浩辉 1肖静 2李忠2

作者信息

  • 1. 广东中烟工业有限责任公司技术中心,广州市荔湾区东沙环翠南路88号 510385
  • 2. 华南理工大学化学与化工学院,广州市天河区五山路381号 510640
  • 折叠

摘要

Abstract

The effects of ozone modification on the surface properties, including specific surface area, pore structure, surface function groups and surface acidic group content, of activated carbon (AC) were studied to develop a flavor containing, slow aroma-releasing filter components for cigarette. The effects of ozone-modified AC were investigated by using 2-cyclopentenone as a model molecule. The results showed that: 1) With the prolonged ozone modifying time, the specific surface area, pore volume and surface acidic group content of AC increased. 2) The number of adsorption peaks of chemical bonds between carbon and oxygen in IR spectrum of ozone-modified AC increased, and the type of surface function groups was also increased after modification. 3) After the ozone treatment, the type of adsorption sites of 2-cyclopentenone on AC increased, which increased the desorption activation energy and adsorption capacity. During machine-smoking of test cigarettes containing the treated AC, ozone modification resulted in the increased release of 2-cyclopentenone, while did not significantly affect the release of routine chemical components in mainstream cigarette smoke.

关键词

臭氧/活性炭/改性/表面性能/脱附活化能/香味物质/缓释/卷烟

Key words

Ozone/Activated carbon/Modification/Surface property/Activation energy of desorption/Aroma component/Slow-release/Cigarette

分类

轻工纺织

引用本文复制引用

余其昌,黄菲,陈森林,黄奕瑕,孔浩辉,肖静,李忠..臭氧改性对活性炭表面性能的影响及在卷烟中的应用[J].烟草科技,2017,50(11):27-32,38,7.

基金项目

中国烟草总公司面上科技项目"提高烟用香精控释效果的多孔固体材料开发及其在卷烟中的应用研究"(中烟办[2012]122号). (中烟办[2012]122号)

烟草科技

OA北大核心CSCDCSTPCD

1002-0861

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