应用化学2017,Vol.34Issue(12):1344-1354,11.DOI:10.11944/j.issn.1000-0518.2017.12.170301
基于大环分子的主客体超分子荧光探针
Host-Guest Supramolecular Fluorescent Probes Based on Macrocyclic Molecules
摘要
Abstract
A number of detection techniques have been developed for the early detection of environmental pollutants and health hazard substances, the prevention and treatment of diseases.Among them, fluorescent probe technique as a convenient, sensitive and visual method has been widely applied. Macrocyclic supramolecular fluorescent probes have gradually attracted the attention of the scientific community.Macrocyclic molecules possess cavities with certain size, which could complex with specific groups to form supramolecules. Therefore, in the design of supramolecular fluorescent probes, the cavity advantage of macrocyclic molecules can be taken into consideration and utilized.In addition, due to easy functionalization, a variety of functional macrocyclic molecules have been synthesized, providing more choices for the design of macrocyclic supramolecular fluorescent probes.This paper reviews the design strategies of macrocyclic supramolecular fluorescent probes with focuses on the chemical composition and detection mechanisms of the probe, which might provide a systematic theoretical guidance for the design of supramolecular fluorescent probes.关键词
荧光分子探针/大环分子/荧光发色团/超分子设计策略/可视化检测Key words
macrocyclic molecule/fluorophore/supramolecular fluorescent probes/design strategies分类
化学化工引用本文复制引用
姚倩芳,程文玉,尹梅贞..基于大环分子的主客体超分子荧光探针[J].应用化学,2017,34(12):1344-1354,11.基金项目
国家自然科学基金(21574009,51521062)、北京市自然科学基金(2142026)、双一流建设专项经费(PY201605)资助 Supported by the National Natural Science Foundation of China(No.21574009, No.51521062), the Beijing Natural Science Foundation(No. 2142026), the Higher Education and High-quality and World-class Universities(No.PY201605) (21574009,51521062)