应用化学2017，Vol.34Issue(12)：1379-1402,24.DOI:10.11944/j.issn.1000-0518.2017.12.170304
亲水性二芳基乙烯荧光分子开关的研究进展
Research Progress on Hydrophilic Photoswitchable Fluorescent Diarylethenes
摘要
Abstract
Photoswitchable fluorescent dithienylethene is one kind of the most typical diarylethene structures. Hydrophilization of photoswitchable fluorescent dithienylethene has become one of the key factors to come true its practical applications as a fluorescence photoswitching probes.Owing to its excellent fatigue resistance and unique thermal bistability, it has been widely studied and applied.This paper reviews the development history of photoswitchable fluorescent thienylethenes, summarizes the mechanism of fluorescence photoswitching mechanisms, describes some important achievements on the foundational research about novel structures and improved properties of photoswitchable fluorescent thienylethene in recent years.We also focus on the systemic overview of the applications of photoswitchable fluorescent dithienylethylene in optical memory, non-destructive read-out, single-molecule fluorescence imaging, bio-imaging, all-optical transistors. In the end, the challenges encountered during the study of diarylethenes are analyzed.It is believable that photoswithcable fluorescent polymers based on dithienylethene is the research direction in the future.Moreover, the promising application of diarylethenes in super-resolution imaging is prospected.关键词
二芳基乙烯/荧光分子开关/亲水性/传感/超分辨成像/荧光开关探针Key words
diarylethene/photoswitchable fluorescent molecules/hydrophilic/sensors/super-resolution imaging/fluorescence photoswitching probes分类
化学化工引用本文复制引用
李冲,陈颖,谢诺华,刘俊霞,范成,周岐元,朱明强..亲水性二芳基乙烯荧光分子开关的研究进展[J].应用化学,2017,34(12):1379-1402,24.基金项目
国家自然科学基金(51673077,51603078,21474034) （51673077,51603078,21474034）
国家重点基础研究发展计划(2015CB755602,2013CB922104) （2015CB755602,2013CB922104）
中央高校基本科研业务费资助(HUST:2016YXMS029) （HUST:2016YXMS029）
武汉光电国家实验室主任基金(2016)资助 Supported by the National Natural Science Foundation of China(No.51673077, No.51603078, No.21474034), the National Basic Research Program of China ( No.2013CB922104, No.2015CB755602 ), the Fundamental Research Funds for the Central Universities ( HUST:2016YXMS029), Director Fund of WNLO （2016）
