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首页|期刊导航|中国塑料|聚氨酯/异氰酸酯改性氧化石墨烯泡沫材料的制备及其性能研究

聚氨酯/异氰酸酯改性氧化石墨烯泡沫材料的制备及其性能研究

谢毓 杜中杰 邹威 王洪 张晨

中国塑料2017,Vol.31Issue(10):20-25,6.
中国塑料2017,Vol.31Issue(10):20-25,6.DOI:10.19491/j.issn.1001-9278.2017.10.004

聚氨酯/异氰酸酯改性氧化石墨烯泡沫材料的制备及其性能研究

Preparation and Properties of Polyurethane/Isocyanate Modified Oxidized Graphene Foam

谢毓 1杜中杰 1邹威 1王洪 1张晨1

作者信息

  • 1. 北京化工大学材料科学与工程学院,碳纤维及功能高分子教育部重点实验室,北京100029
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摘要

Abstract

In this work,graphene oxide (GO) was first prepared by the Hummers method and then was surface-modified with isophorone diisocyanate to obtain the isocyanate-modified GO.The polyurethane-matrix composite foams were prepared by incorporation of the isocyanate-modified GO.Effect of the isocyanate-modified GO on porous structure,thermal conductivity and mechanical properties of the composite foam were investigated.The composite foams achieved the maximum compressive strength and compressive modulus with the addition of only 0.5 % isocyanate-modified GO.However,there is no distinct influence on thermal conductivity observed.Moreover,the composite foams also gained an improvement in glass transition temperature and energy storage modulus.

关键词

氧化石墨烯/异佛尔酮二异氰酸酯/聚氨酯/玻璃化转变温度/导热/力学性能

Key words

graphite oxide/isophorone diisocyanate/polyurethane/glass transition temperature/thermal conductivity/mechanical property

分类

化学化工

引用本文复制引用

谢毓,杜中杰,邹威,王洪,张晨..聚氨酯/异氰酸酯改性氧化石墨烯泡沫材料的制备及其性能研究[J].中国塑料,2017,31(10):20-25,6.

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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