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成核剂对聚丙烯结晶行为的研究

姜艳峰 安彦杰 李瑞 国海峰 葛腾杰 王世华

中国塑料2017,Vol.31Issue(10):26-32,7.
中国塑料2017,Vol.31Issue(10):26-32,7.DOI:10.19491/j.issn.1001-9278.2017.10.005

成核剂对聚丙烯结晶行为的研究

Effects of Nucleating Agents on Crystallization Behavior of Polypropylene

姜艳峰 1安彦杰 1李瑞 1国海峰 1葛腾杰 1王世华1

作者信息

  • 1. 中国石油天然气股份有限公司石油化工研究院大庆化工研究中心,黑龙江大庆163714
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摘要

Abstract

Effects of phosphate nucleating agents,carboxylate nucleating agents,rosin type nucleating agents and sorbitol type nucleating agents on crystallization behavior of isotactic polypropylene (i-PP) were investigated by Fourier-transform infrared spectroscopy,powder X-ray diffraction,differential scanning calorimetry and polarizing light microscopy.The results indicated that the crystallization kinetics of i-PP was significantly influenced by its crystallization rate,crystallization temperature and crystallinity because of the difference in the structure of nucleating agents.Among these nucleating agents,the phosphate nucleating agents exhibit the shortest half time for the crystallization of i-PP,and its crystallization temperature was up to 129.8 ℃.

关键词

成核剂/聚丙烯/结晶行为

Key words

nucleating agent/polypropylene/crystallization behavior

分类

化学化工

引用本文复制引用

姜艳峰,安彦杰,李瑞,国海峰,葛腾杰,王世华..成核剂对聚丙烯结晶行为的研究[J].中国塑料,2017,31(10):26-32,7.

基金项目

中国石油天然气股份有限公司炼油与化工板块项目(2013B-2703-0317) (2013B-2703-0317)

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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