中国塑料2017，Vol.31Issue(10)：33-39,7.DOI:10.19491/j.issn.1001-9278.2017.10.006
过渡金属植酸盐的制备及其在PVC中的阻燃应用
Synthesis of Transition Metallic Phytates and Its Applications in PVC as an Efficient Flame Retardant
程路瑶 1武伟红 2孟伟华 1许硕 1屈红强 1徐建中1
作者信息
- 1. 河北大学化学与环境科学学院,河北保定071002
- 2. 河北农业大学理学院,河北保定071001
- 折叠
摘要
Abstract
Transition metallic phytates (M-Phyt) containing different rare earth elements were synthesized by a direct precipitation method,and then it was used as a flame-retardant and smoke suppressant for flexible PVC.It indicated that the prepared M-Phyt particles exhibited an irregular shape.Char yields of M-Phyt in nitrogen were in an order of Mn-Phyt＞Co-Phyt＞Fe-Phyt＞Ni-Phyt.PVC compound containing 15 wt ％ Co-Phyt showed the highest LOI,which was improved from 24.9 ％ to 28.3 ％,and its SDR reached 75.09 ％.Fe-Phyt exhibited an optimum smoke suppression effect on PVC by reducing SDR of PVC/Fe-Phyt compound from 94.55 ％ to 48.96 ％,and LOI of PVC/Fe-Phyt compound was 27.7 ％.Char yields of the compounds were greatly improved with the addition of M-Phyt.Char yield of PVC/Co-Phyt composite was as high as 22.08 wt ％,but char yield of PVC/Ni-Phyt composite increased by 9.09 ％.关键词
过渡金属/植酸/抑烟/软质聚氯乙烯Key words
transition metallic/phytic acid/smoke suppression/flexible poly(vinyl chloride)分类
化学化工引用本文复制引用
程路瑶,武伟红,孟伟华,许硕,屈红强,徐建中..过渡金属植酸盐的制备及其在PVC中的阻燃应用[J].中国塑料,2017,31(10):33-39,7.
