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活性炭物理参数对铅炭电池的影响

孙德龙 胡晨 汪浩 金翼

电池2017,Vol.47Issue(5):281-285,5.
电池2017,Vol.47Issue(5):281-285,5.DOI:10.19535/j.1001-1579.2017.05.007

活性炭物理参数对铅炭电池的影响

Effect of physical parameters of activated carbon on lead-carbon battery

孙德龙 1胡晨 2汪浩 1金翼2

作者信息

  • 1. 北京工业大学材料科学与工程学院,北京100124
  • 2. 中国电力科学研究院新能源与储能运行控制国家重点实验室,北京100192
  • 折叠

摘要

Abstract

Activated carbons with different specific surface area and different pore size distribution were prepared by chemical activation method,then lead-carbon composite electrode and lead-carbon battery were prepared.The lead carbon battery,which contained activated carbon C4-5h,C5-5h and C6-5b (The specific surface area were 1 361.1 m2/g,1 638.5 m2/g,1 390.1 m2/g,among which C4-5h pore size distribution was concentrated,C5-5h and C6-5h pore size distribution was relatively dispersed.)completed 35 843 cycles,30 174 cycles and 25 500 cycles before the voltage reached the lower limit voltage respectively.After watching the electrode material by scanning electron microscopy,it was found that the accumulation of PbSO4 crystals could be inhibited by C4-5h.The problem of PbSO4 crystals arranged on the surface of the negative electrode plate closely could be solved by C5-5h and C6-5h.The cycle performance of lead-carbon batteries was enhanced by all three kinds of activated carbon.

关键词

铅炭电池/活性炭/物理参数/循环性能/电化学性能

Key words

lead-carbon battery/activated carbon/physical parameter/cycle performance/electrochemical performance

分类

信息技术与安全科学

引用本文复制引用

孙德龙,胡晨,汪浩,金翼..活性炭物理参数对铅炭电池的影响[J].电池,2017,47(5):281-285,5.

基金项目

国家电网公司科技项目(DG71-17-009),北京市教委科技计划项目(KZ20171005009) (DG71-17-009)

电池

OA北大核心CSCDCSTPCD

1001-1579

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